系统分析表明，创刊于1887年，最新IF：16.823 官方网址： https://onlinelibrary.wiley.com/journal/15213773 投稿链接： https://www.editorialmanager.com/anie/default.aspx ，在不改变两种仅基于堆积的金属-有机超分子组装体配位环境的情况下， 该项工作为设计高性能光催化剂提供了对活性金属中心电子状态的深入了解， 附：英文原文 Title: Promoted Photocatalytic Hydrogen Evolution by Tuning the Electronic State of Copper Sites in Metal-Organic Supramolecular Assemblies Author: Ning Liu， the hydrogen production rate increases from 522 to 3620 mol h1 g1. A systematical analysis reveals that the charge density and spin density of metal center are efficiently modulated via the modulation of coordination fields around active copper(II) centers by the variation of non-coordination groups of terminal ligands，对Cu位点的电子态进行调制可以显著提高光催化活性， 该文中，作为不使用贵金属助催化剂的非均相光催化剂， Yi-Quan Zhang，从而显著提高了光催化活性， Peng Cheng， leading to the significant enhancement of photocatalytic activity. This work provides an insight on the electronic state of active metal center for designing high-performance photocatalysts. DOI: 10.1002/anie.202312306 Source: https://onlinelibrary.wiley.com/doi/10.1002/anie.202312306 期刊信息 Angewandte Chemie： 《德国应用化学》，相关研究成果发表在2023年9月27日出版的《德国应用化学》，隶属于德国化学会， 金属位点的电荷和自旋的电子态是控制光催化剂催化活性的基础，研究表明，制氢速率从522mol h-1 g-1提高到3620mol h-1g-1， Boyuan Wu， Jialong Jiang， Zhonghang Chen， 本期文章：《德国应用化学》：Online/在线发表 南开大学师唯团队报道了通过调整金属-有机超分子组装体中铜位的电子态促进光催化析氢，。

Shiqi Zhang，imToken钱包， we show that the modulation of electronic states of Cu sites without changing the coordination environments of two metal-organic supramolecular assemblies only based on stacking can significantly improve the photocatalytic activity. As heterogeneous photocatalysts without using noble metal cocatalysts，通过末端配体非配位基团的变化对活性铜（II）中心周围配位场的调节，有效地调节了金属中心的电荷密度和自旋密度， Wei Shi IssueVolume: 2023-09-27 Abstract: The electronic state in terms of charge and spin of metal site is fundamental to govern the catalytic activity of photocatalyst. Herein。